Water saturation of natural gas feeds for temperature swing adsorption in molecular sieve unit ng feeds to the dehydration unit consists of h 2 oco 2 ch 4 streams previously saturated with water in the process flow diagram pfd shown in fig. Natural gas dehydration by desiccant materials core. Not yet discussed is the type of molecular sieve to be used. Absorption and refrigeration with hydrate inhibition is the most common dehydration process used to meet pipeline sales specifications. Pdf a study of the dehydration process of natural gas in iraqi. Msdu gas phase molecular sieve dehydration wit pressure adsorption and vacuum psavsa swing desorption for 210% water this design passes the wet alcohol or solvent stream in vapor state at a controlled pressure through a column filled with molecular sieve beads. Downloads certificates, brochures, safety sheets zeochem. Due to the special performance of preferential adsorption, molecular sieve is widely used for gas dehydration, gas purification and gas production. Middlesex gases specialty gas equipment molecular sieves. The active constituent of a molecular sieve adsorbent is a microporous, crystalline, alkalimetal aluminosilicate, referred to as. Adsorption molecular sieve, silica gel, or activated alumina. A molecular sieve dehydration unit is actually a collection of components that support the saturation and regeneration of the material in order to remove water from the natural gas stream.
Some of the more common types of molecular sieves and some typical applications include the following. Optimal design and operation of molecular sieve gas dehydration. As previously mentioned, a molecular sieve is composed of a zeolite and a binder, typically clay. The 3a molecular sieve can remove moisture in both liquid and gas applications. Molecular sieves are the product of choice for the deep dehydration required by lng liquefied natural gas or ngl natural gas liquids facilities. Molecular sieve is a material with pores very small holes of uniform size. Some physical properties of pure teg are given in the following text. Pdf a study of the dehydration process of natural gas in.
Molecular sieve valves process overview in gas processing, molecular sieving is a common practise to remove impurities e. Specifically, they discussed the benefits of standby time in the adsorption dehydration processes and impact of feed gas conditions. Glycol dehydration systems are not only efficient at removing water from a natural gas stream, they also remove benzene, toluene, ethylbenzene, and xylene btex as well as other volatile organic compounds vocs. Among our experience there are units in sour service more than 20 ppmv of h 2 s, the largest silica gel gas dehydration plants in the world and units located offshore. Glycol dehydration cannot get to these low water levels mole sieves used for this service. Natural gas dehydration 5 temperatures and the absorbed water is boiled out from teg during regeneration in a reboiler at high temperatures. In order to achieve such speci cations, the raw gas must pass through a series of puri cation steps, which compose the socalled natural gas chain. With over 2,500 operating units worldwide, uop is a leading global commercial expert in molecular sieves for gas and liquid processing.
The raw natural gas extracted from production wells contains many impurities that must be removed in order to achieve the speci cations of the liqui ed natural gas lng andor the pipeline gas. Formation of the water phase will control the water content in the gas phase. Molecular sieves 4a is a perfect desiccant to dehydrate targeted natural gases and compressed air like argon, methane, available in beads, pellets and powdered form. For the love of physics walter lewin may 16, 2011 duration. The sodium form of the type x crystal structure, is an alkalai metal aluminosilicate.
This work shows a study of natural gas dehydration using 3a molecular sieve as a type of solid desiccant materials, the scope of this work was to build up a pilot. The combination of 2 to 3 beds, a heater, a condenser, and a dust filter work together to dry natural gas. Pdf natural gas dehydration by desiccant materials mustafa. In the molecular sieve process, the produced gas is a byproduct of oil production and reinjection is required to maintain reservoir pressure. Natural gas dehydration with molecular sieve interra global. Mol sieve dehydration is a process where water vapors are removed from the gas streams using the highly effective desiccant material known as molecular sieves.
Type 3a is used for drying natural gas, ethanol and reactive monomers. Natural gas liquids and condensed higher hydrocarbons can also be recovered from ng by cooling. Taking the example of natural gas drying with molecular sieves, the dehydration unit is typically designed by the molecular sieve manufacturer. On molecular sieves for cracked gas dehydration in an ethylene plant, the cracked gas is saturated with water before compression and after each in tercooler stage, therefore it needs to be dried before fractionation to prevent the presence of ice at low temperatures. How to order type quantity 3a 4a 5a x 116beads 8x12mesh. As the wet or sour stream is processed in one column, the other column is being regenerated. Find white papers, safety brochures, technical data sheets and many more zeochem resources here. Amazing zeolites and their new role in natural gas purification. Modelling of natural gas sweetening and dehydration processes.
This work shows a study of natural gas dehydration using 3a molecular sieve as a type of solid desiccant materials, the scope of this work was to build up a pilot scale unit for a natural gas dehy dration as simulation of actual existing plant for egyptian western desert gas company wdgc. The issue is well documented in the literature, but there remains a difference of opinion as to whether there is advantage to using a 3a type molecular sieve over. These pore diameters are similar in size to the molecules, and thus large molecules cannot enter or be absorbed while the smaller molecules can go in. Gas dehydration is the process of removing water vapor from. Capex and opex considerations for gas dehydration technologies joeri olijhoek, frames gas treatment. Molecular sieve type 4a natural gas dehydration agent. Optimal design and operation of molecular sieves for gas. Natural water of hydration is removed from this network by heating to produce uniform cavities which selectively adsorb molecules of a specific size. Contaminants of natural gas are polar compounds water, co2 and hydrogen sulphide h2s, for instance and these are strongly adsorbed by zeolite molecular sieves. Natural gas dehydration by molecular sieves duration.
China industrial type 4a molecular sieve for moisture control desiccant pack, find details about china factory supply molecular sieve 4a, molecular sieve x from industrial type 4a molecular sieve for moisture control desiccant pack zhengzhou city mantanghong abrasives co. Molecular sieves technical information bulletin sigma. This work shows a study of natural gas dehydration using 3a molecular sieve as a type of solid desiccant materials, the scope of this work was. This does not only involve choosing the right adsorbents, but also designing the adsorption and regeneration.
Ng can be advantageously cooled using the joulethompson effect jt effect. The dehydration of natural gas by any means is done primarily to prevent the formation of gas hydrates during the trans. This tip of the month shows how a short cut method scm, after one performance test run ptr, may be used to estimate the life of a type 4a molecular sieve dehydrating a watersaturated feed of natural gas. In iraqi north gas company, the molecular sieve of type 4a is used to remove. Zeochem molecular sieve adsorbents zeochem manufactures a wide range of zeolites used as molecular sieve adsorbents. Pdf natural gas dehydration by desiccant materials researchgate. China industrial type 4a molecular sieve for moisture. This type of lineup is possible only for dhus designed for water removal, as knocking out the water in the regeneration ko drum provides a drain from the. A contributing factor to molecular sieve deactivation is the deposition of liquids, such as amines, that originate from the upstream amine unit being deposited on the molecular sieve. Valvtechnologies v14 metal seated ball valves background.
The condensation method is therefore usually applied for simultaneous dehydration and recovery of natural gas liquids. One of the common dehydration system design strategies is for plants to use a slipstream of the residue gas to function as both the heating medium for the beds and the. Natural gas is commercially dehydrated in one of three ways. Molecular sieves are often utilized in the petroleum industry, especially for drying gas streams. Molecular sieves molecular sieve adsorbents zeochem. As a result, the natural gas processing industry uses uops molsiv adsorbents for natural gas dehydration, mercury removal, co2 removal, natural gas lpg desulfurization and ammonia synthesis gas purification. Molecular sieve dehydration of biodiesel dehydration and puri.
Different types of molecular sieves are used in industrial natural gas dehydration. For example, in the liquid natural gas lng industry, the water content of the gas needs to be reduced to less than 1 ppmv to prevent blockages caused by ice. Type 3a is used in the production of insulated glass, refrigerant drying, general moisture removal and the drying of natural gas, hydrocarbon liquids, ethanol and reactive monomers such as olefins. A study of the dehydration process of natural gas in iraqi north gas company and the treatment methods of molecular sieve problems supervised by. This work shows a study of natural gas dehydration using 3a molecular sieve as a type of solid desiccant materials, the scope of this work was to build up a pilot scale unit for a natural gas. Dehydration of natural gas is needed to remove the water that is associated with. Molecular sieves are crystalline metal aluminosilicates having a threedimensional interconnecting network of silica and alumina tetrahedra.
Molecular desiccant in natural gas dehydration process. Twotower vs threetower system the petroskills may 2015 2 and october 2015 tip of the month totm 3 discussed the efficient operation of molecular sieve dehydration units. Molecular sieves for natural gas treatment are loaded in vertical adsorbers, most of the time on a support system. Failure analysis and faults diagnosis of molecular sieve. A typical system consists of two or more columns packed with molecular sieve material. This is typically done by chilling and by adsorption using molecular sieves. Molsievebased dehydration technology desiccant dehydration dolphin onshore gas plant project molecular sieve package 3d drawing dumbarton field development molecular sieve package replicantes frames gas treatment dr. Gases to be dehydrated cover straight natural gas, through heavier associated gases, and sour gases of. In natural gas systems, removing water vapor reduces pipeline corrosion and eliminates line blockage caused by hydrate formation. This work shows a study of natural gas dehydration using 3a molecular sieve as a type of solid desiccant materials, the scope of this work was to build up a pilot scale unit for a natural gas dehydration as simulation of actual existing plant for egyptian western desert gas company wdgc. Optimal design and operation of molecular sieve gas. Natural gas dehydration by desiccant materials sciencedirect.